Wellcome to the forum Ikbonham, Greetings from the other side of the Globe
I love doing Grafting including avocadoes
I believes as long as the cambium layer of both graft and scion are in good contact it will works
it is even better to use an actively growing root stock, one that is still soft like a young stem from seedling (most of the time I graft scion to a seedling root stock, with seed still attached)
But grafting to a large hardwood is also works, if the root stock are too big or the wood is hard, you can insert the scion right between bark and wood, exactly between cambium layer. I wish to do few grafting in near future using this method too
mean while before that, below is my newly result of grafting a variegated scion to a seedling root stock
I remove the sprout of the rootstock